5-chloro-1-phenylpentan-1-one

  • CAS:942-93-8
  • MF:C11H13 Cl O
  • Purity:99%
  • Molecular Weight:196.677
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Product Details

  • CAS: 942-93-8
  • MF: C11H13 Cl O
  • Buy Quality 5-chloro-1-phenylpentan-1-one 942-93-8 In Stock with Immediately Delivery

    • Molecular Formula:C11H13 Cl O
    • Molecular Weight:196.677
    • Vapor Pressure:0.000871mmHg at 25°C 
    • Boiling Point:304.5°Cat760mmHg 
    • Flash Point:162.3°C 
    • PSA:17.07000 
    • Density:1.081g/cm3 
    • LogP:3.27840 

    5-chloro-1-phenylpentan-1-one(Cas 942-93-8) Usage

    General Description

    5-chloro-1-phenylpentan-1-one, also known as 5-Cl-PP, is an organic compound with the chemical formula C11H13ClO. It is a clear, colorless liquid with a slightly sweet odor that is used as a precursor in the synthesis of pharmaceuticals and other organic compounds. 5-Cl-PP is also known to have various industrial uses, such as in the production of fragrances and flavorings. Its chemical structure contains a chlorine atom and a phenyl group, making it a versatile building block for the creation of a wide range of chemical compounds. Due to its potential for use in the production of various products, 5-chloro-1-phenylpentan-1-one is an important compound in the field of organic chemistry and chemical synthesis.

    InChI:InChI=1/C11H13ClO/c12-9-5-4-8-11(13)10-6-2-1-3-7-10/h1-3,6-7H,4-5,8-9H2

    942-93-8 Relevant articles

    In-situ-generation of alkylsilyl peroxides from alkyl hydroperoxides and their subsequent copper-catalyzed functionalization with organosilicon compounds

    Xu, Weiping,Zhong, Wenfeng,Yang, Qin,Kato, Terumasa,Liu, Yan,Maruoka, Keiji

    , (2021/06/16)

    Alkylsilyl peroxides were generated in s...

    Copper-catalyzed radical ring-opening halogenation with HX

    Bai, Ming,Duan, Xin-Hua,Guo, Li-Na,Liu, Shuai,Sun, Qing-Xin,Xu, Peng-Fei

    , p. 8652 - 8655 (2021/09/04)

    An efficient copper-catalyzed radical ri...

    Ni-Catalyzed C(sp2)-H alkylation ofN-quinolylbenzamides using alkylsilyl peroxides as structurally diverse alkyl sources

    Kano, Taichi,Maruoka, Keiji,Matsumoto, Akira,Sakurai, Shunya,Tsuzuki, Saori

    supporting information, p. 7942 - 7945 (2021/08/17)

    A Ni-catalyzed direct C-H alkylation ofN...

    Cu-Catalyzed: O -alkylation of phenol derivatives with alkylsilyl peroxides

    Sakurai, Shunya,Kano, Taichi,Maruoka, Keiji

    supporting information, p. 81 - 84 (2021/01/14)

    A Cu-catalyzed O-alkylation of phenol de...

    942-93-8 Process route

    1-phenylcyclopentanol
    10487-96-4

    1-phenylcyclopentanol

    5-Chloro-1-phenyl-1-pentanone
    942-93-8

    5-Chloro-1-phenyl-1-pentanone

    Conditions
    Conditions Yield
    With 1,10-Phenanthroline; tert-butylhypochlorite; silver trifluoromethanesulfonate; In acetonitrile; at 20 ℃; for 48h; regioselective reaction; Inert atmosphere; Schlenk technique;
    80%
    Multistep reaction; (i) aq. NaOCl, AcOH, (ii) (heating);
    With tetra(n-butyl)ammonium hydrogensulfate; hypochloric acid; In dichloromethane; chlorobenzene; at 20 ℃; for 0.5h; pH=8.6 - 9.6;
    Multi-step reaction with 2 steps
    1: dihydrogen peroxide; sulfuric acid / water / 18 h / 0 - 20 °C / Inert atmosphere
    2: copper(l) iodide; chloro-trimethyl-silane; triethylamine / N,N-dimethyl-formamide / 12 h / 28 °C / Inert atmosphere
    With copper(l) iodide; chloro-trimethyl-silane; sulfuric acid; dihydrogen peroxide; triethylamine; In water; N,N-dimethyl-formamide;
    Multi-step reaction with 2 steps
    1: dihydrogen peroxide; sulfuric acid / water; dichloromethane / 12 h / 0 - 25 °C / Schlenk technique; Inert atmosphere
    2: copper diacetate; hydrogenchloride / 1-methyl-pyrrolidin-2-one; water / 2 h / 25 °C / Schlenk technique; Inert atmosphere; Sealed tube
    With hydrogenchloride; sulfuric acid; dihydrogen peroxide; copper diacetate; In 1-methyl-pyrrolidin-2-one; dichloromethane; water;
    δ-chlorovaleronitrile
    6280-87-1

    δ-chlorovaleronitrile

    phenylmagnesium bromide
    100-58-3

    phenylmagnesium bromide

    5-Chloro-1-phenyl-1-pentanone
    942-93-8

    5-Chloro-1-phenyl-1-pentanone

    Conditions
    Conditions Yield
    δ-chlorovaleronitrile; phenylmagnesium bromide; In tetrahydrofuran; at 0 - 20 ℃; for 12h;
    With hydrogenchloride; water; In tetrahydrofuran; for 3h; Reflux;
    81%

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    942-93-8 Downstream products

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      dl-5-Chlor-1-(4-fluorphenyl)-1-phenyl-pentanol

    Antioxidant BHT 264

    CAS:128-37-0

    Purity:99%

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